Tried it last night. Didn't seem to go into gear at any higher speed but I agree it should be easier on the synchros.
should at least feel lighter when you shift, if you go from high to low you can help it if transmission is in gear and you rev the engine before pressing the clutch and keep slight pressure on the t-case shifter, would help bringing the transmission output shaft up in revs. The other thing you can try is to have the trans in neutral and keep slight pressure on the stick to give the shaft time to rev (something like when you try to shift in 1st at higher speed, you need to put slight pressure on the stick but not pushing it too hard before actually shifting into gear, the syncro would bring the gear/shaft up to revs by friction, if the difference is high it takes a bit to get there)
if you already did all that try the front (rear in neutral) and see if it's any different, wondering if the other syncro is not up to par or maybe needs some wear to get broken in (same with the transmission, sometimes when you replace the syncros it takes a little bit to get it working smooth, since you don't shift the t-case on a regular basis would take a while to get there).